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Type: Artigo de periódico
Title: Synthesis of acylsilanes via oxidative hydrolysis of 2-silyl-1,3-dithianes mediated by N-bromosuccinimide
Author: Patrocinio, AF
Moran, PJS
Abstract: The oxidative method for the hydrolysis of 1,3-dithianes was applied to 2-silyl-1,3-dithianes using N-bromosuccinimide providing acylsilanes with good yields under a short reaction period. The oxidation of aroylsilanes to carboxylic acid was prevented by the addition of bases and the lowering of the reaction temperature. (C) 2000 Elsevier Science S.A. All rights reserved.
Subject: aroylsilanes
Country: Suíça
Editor: Elsevier Science Sa
Citation: Journal Of Organometallic Chemistry. Elsevier Science Sa, v. 603, n. 2, n. 220, n. 224, 2000.
Rights: fechado
Identifier DOI: 10.1016/S0022-328X(00)00181-9
Date Issue: 2000
Appears in Collections:Unicamp - Artigos e Outros Documentos

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