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Type: Artigo de periódico
Title: Synthesis and characterization of T[Ni(CN)(4)] center dot 2pyz with T=Fe, Ni, pyz=pyrazine: Formation of T-pyz-Ni bridges
Author: Lemus-Santana, AA
Rodriguez-Hernandez, J
Gonzalez, M
Demeshko, S
Avila, M
Knobel, M
Reguera, E
Abstract: The formation of T-pyz-Ni bridges (pyz= pyrazine) in the T[Ni(CN)(4)] center dot 2pyz series is known for T=Mn, Zn, Cd and Co but not with T=Fe, Ni. In this contribution the existence of such bridges also for T=Fe, Ni is discussed. The obtained pillared solids, T[Ni(CN)(4)] center dot 2pyz, were characterized from XRD, TG, UV-Vis, IR, Raman, Mossbauer and magnetic data. Their crystal structures were refined in the orthorhombic Pmna space group from XRD powder patterns. The structural behavior of these solids on cooling down to 77 K was also studied. In the 180-200 K temperature range the occurrence of a structural transition to a monoclinic structure (P2(1)/c space group) was observed. No temperature induced spin transition was observed for Fe[Ni(cN)(4)]. 2pyz. The iron (II) was found to be in high spin electronic state and this configuration is preserved on cooling down to 2 K. The magnetic data indicate the occurrence of a low temperature weak anti-ferromagnetic interaction between T metal centers within the TINi(CN)(4)] layer. In the paramagnetic region for Ni[Ni(CN)4] center dot 2pyz, a reversible temperature induced spin transition for the inner Ni atom was detected. (C) 2011 Elsevier Inc. All rights reserved.
Subject: Crystal chemistry
Structural study
Layered compound
Pillared solid
Spin transition
Country: EUA
Editor: Academic Press Inc Elsevier Science
Rights: fechado
Identifier DOI: 10.1016/j.jssc.2011.06.011
Date Issue: 2011
Appears in Collections:Unicamp - Artigos e Outros Documentos

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