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|Type:||Artigo de periódico|
|Title:||The mechanism of Troger's base formation probed by electrospray ionization mass spectrometry|
|Abstract:||Using direct infusion electrospray ionization mass and tandem mass spectrometric experiments [ESI-MS(/MS)], we have performed on-line monitoring of some reactions used to form Troger's bases. Key intermediates, either as cationic species or as protonated forms of neutral species, have been intercepted and characterized. The role of urotropine as the methylene source in these reactions has also been accessed. Reaction pathways shown by ESI-MS(/MS) have been probed by gas-phase ion/molecule reactions, and an expanded mechanism for Troger's base formation based on the mass spectrometric data has been elaborated.|
|Editor:||Amer Chemical Soc|
|Citation:||Journal Of Organic Chemistry. Amer Chemical Soc, v. 72, n. 11, n. 4048, n. 4054, 2007.|
|Appears in Collections:||Unicamp - Artigos e Outros Documentos|
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