Please use this identifier to cite or link to this item:
Type: Artigo de periódico
Title: The role of stereoelectronic interactions in the conformational isomerism of some phosphorus-containing model compounds
Author: Freitas, MP
Rittner, R
Tormena, CF
Abraham, RJ
Abstract: The rotational isomerism of model phosphorus-containing compounds was evaluated by using theoretical methodologies. The trans rotamer of chloromethylphosphonic acid dichloride (1) was found to be the prevailing form in the gas phase and in non-polar solvents, with an inverse behaviour from chloroform solution. Although the use of direct spin-spin coupling constants (SSCCs) do not apply for the quantitative determination of conformers in 1, due to the small dependence of J with conformation, the observed measurements and calculated individual couplings suggest that the gauche conformer is progressively stabilized with increasing the solvent polarity. In addition, theoretical calculations at the CBS-Q level for the corresponding phosphine of 1 (compound 2) showed the gauche rotamer as the prevailing one in the isolated state. Natural Bond Orbital (NBO) analysis indicated that steric and electrostatic effects rule the rotational isomerism of 1, while the anomeric effect n(P) -> sigma(CCl)* also plays an important role on the conformational equilibrium of 2. Copyright (C) 2008 John Wiley & Sons, Ltd.
Subject: conformational analysis
solvation theory
phosphorus-containing compounds
classical effects
anomeric effect
Country: Inglaterra
Editor: John Wiley & Sons Ltd
Rights: fechado
Identifier DOI: 10.1002/poc.1372
Date Issue: 2008
Appears in Collections:Artigos e Materiais de Revistas Científicas - Unicamp

Files in This Item:
File Description SizeFormat 
WOS000257090800010.pdf190.46 kBAdobe PDFView/Open

Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.