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Type: Artigo de periódico
Title: Self-immobilization of poly(methyloctylsiloxane) on high-performance liquid chromatographic silica
Author: Collins, KE
Bottoli, CBG
Vigna, CRM
Bachmann, S
Albert, K
Collins, CH
Abstract: Poly(methyloctylsiloxane) (PMOS) was deposited on HPLC silica by a solvent evaporation procedure and this material was then extracted, using a good solvent for the PMOS, after different time periods, to remove unretained liquid polymer. Solvent extraction data reveal changes which occur at ambient temperature as a function of the time interval between particle loading and extraction. The quantity of PMOS remaining on the silica after extraction, as determined by elemental analysis for carbon, is attributed to strongly adsorbed polymer. This phenomenon is termed self-immobilization. Solid-state Si-29 NMR spectra indicate the formation of a silicon species with a different chemical shift than the original PMOS. These new signals are attributed to a combination of different adsorbed and chemically bonded groups. (C) 2004 Elsevier B.V. All rights reserved.
Subject: stationary phases
nuclear magnetic resonance spectroscopy
poly (methyloctylsiloxane)
Country: Holanda
Editor: Elsevier Science Bv
Rights: fechado
Identifier DOI: 10.1016/j.chroma.2003.12.045
Date Issue: 2004
Appears in Collections:Unicamp - Artigos e Outros Documentos

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