Please use this identifier to cite or link to this item: http://repositorio.unicamp.br/jspui/handle/REPOSIP/70116
Type: Artigo de periódico
Title: PREPARATION AND MOSSBAUER STUDY OF IRON-MERCURY COMPLEXES CONTAINING ISOCYANIDE AND CARBONYL LIGANDS
Author: MORIGAKI, MK
MACHADO, LC
LARICA, C
DIAS, GHM
Abstract: Complexes [Fe(t-BuNC)(n)(CO)(5-n)] (n = 1 or 2) react with equimolar amounts of mercury(II) halides in acetone to form neutral iron-mercury adducts [Fe(t-BuNC)(CO)(4)(HgX(2))] and [Fe(t-BuNC)(2)(CO)(3)(HgX(2))] (X = Cl or I), while [Fe(t-BuNC)(5)] reacts with solid mercury halides in petroleum ether to give the salts [Fe(t-BuNC)(5)(HgX)]HgX(3) (X = Br or I). Product assessment was based upon analytical and spectroscopic data, the Mossbauer effect and on molar conductivity studies.
Country: Inglaterra
Editor: Chapman Hall Ltd
Rights: fechado
Identifier DOI: 10.1007/BF00980411
Date Issue: 1994
Appears in Collections:Artigos e Materiais de Revistas Científicas - Unicamp

Files in This Item:
File Description SizeFormat 
WOSA1994PZ49100010.pdf351.86 kBAdobe PDFView/Open


Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.