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Type: Artigo de periódico
Title: Preparation and Mossbauer studies of iron-mercury mixed isocyanide-carbonyl complexes
Author: Morigaki, MK
Machado, LC
da Silva, EM
Larica, C
Filho, AB
Dias, GHM
Abstract: The reactions of [Fe(t-BuNC)(3)(CO)(2)] with HgX2 (X = Cl. Br or I) give two different types of iron-mercury halide complex, depending on the molar ratio of reactants used. An equimolar ratio of the reactants produces the neutral adducts [Fe(t-BuNC)(3)(CO)(2)(HgX2)], whereas two equivalents of HgX2 generate the electrolytes [Fe(t-BuNC)(3)(CO)(2)(HgX)]HgX3. The Mossbauer, i.r. data, and conductivity measurements of these complexes are presented and discussed in terms of their chemical structures and bonding.
Country: Holanda
Editor: Kluwer Academic Publ
Rights: fechado
Identifier DOI: 10.1023/A:1006924105568
Date Issue: 1999
Appears in Collections:Artigos e Materiais de Revistas Científicas - Unicamp

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