Please use this identifier to cite or link to this item: http://repositorio.unicamp.br/jspui/handle/REPOSIP/69745
Type: Artigo de periódico
Title: Organofunctionalized Amazon smectite for dye removal from aqueous medium-Kinetic and thermodynamic adsorption investigations
Author: Guerra, DL
Silva, WLL
Oliveira, HCP
Viana, RR
Airoldi, C
Abstract: The objective of this study is to examine the adsorption behavior of Sumifix Brilliant Orange 3R textile dye from aqueous solution on smectite sample, an abundant Amazon clay. The original smectite clay mineral has been collected from Amazon region, Brazil. The compound 2-aminomethylpyridine was anchored onto smectite surface by heterogeneous route. The ability of these materials to remove the Sumifix Brilliant Orange 3R textile dye from aqueous solution was followed by a series of adsorption isotherms, using a batchwise process. The maximum number of moles adsorbed was determined to be 1.26 and 2.07 mmol g(-1) for natural and modified clay samples, respectively. The energetic effects caused by dye cations adsorption were determined through calorimetric titrations. Thermodynamics indicated the existence of favorable conditions for such dye-nitrogen interactions. (C) 2010 Published by Elsevier B.V.
Subject: Smectite
Phyllosilicate
Sumifix Brilliant Orange 3R
Adsorption
Kinetic
Calorimetry
Country: Holanda
Editor: Elsevier Science Bv
Rights: fechado
Identifier DOI: 10.1016/j.jhazmat.2010.11.054
Date Issue: 2011
Appears in Collections:Artigos e Materiais de Revistas Científicas - Unicamp

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