Please use this identifier to cite or link to this item: http://repositorio.unicamp.br/jspui/handle/REPOSIP/69644
Type: Artigo de periódico
Title: Host hydrated barium phenylphosphonate/guest heterocyclic amine intercalation energetics by calorimetric titration
Author: Lazarin, AM
Airoldi, C
Abstract: The heterocyclic amines 2,6-lutidine, pyrazine, piperazine and piperidine were intercalated into layered crystalline hydrated barium phenylphosphonate, Ba(HO3PC6H5)(2)center dot H2O, through a batch method in ethanolic solution, to give the maximum amounts 0.39, 0.82, 2.80 and 5.50 mmol g(-1), respectively. The original host interlayer distance (d) of 1532 put increased after intercalation for piperazine (1752 pm) and piperidine (2112 pm) molecules, while for 2,6-lutidine and pyrazine molecules d values were maintained. The enthalpy of intercalation gave -5.60 +/- 0.10, -1.00 +/- 0.02, -9.55 +/- 1.00 and -30.70 +/- 0.68 kJ mol(-1) for the sequence of heterocyclic amines. The Gibbs free energies are negative and entropies are positive for intercalation. (c) 2005 Elsevier B.V. All rights reserved.
Subject: calorimetry
heterocyclic amine
barium phenylphosphonate
intercalation
thermochemistry
Country: Holanda
Editor: Elsevier Science Bv
Rights: fechado
Identifier DOI: 10.1016/j.tca.2005.12.005
Date Issue: 2006
Appears in Collections:Unicamp - Artigos e Outros Documentos

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