Please use this identifier to cite or link to this item: http://repositorio.unicamp.br/jspui/handle/REPOSIP/69024
Type: Artigo de periódico
Title: Hydrophobic polymer modification with ionic reagents: Polystyrene staining with water-soluble dyes
Author: Braga, M
Leite, CAP
Galembeck, F
Abstract: Homopolymer polystyrene films tinted with methylene blue and other hydrophilic cationic dyes are made following anew two-step procedure: dye adsorption in latex particles, followed by polymer plasticization with a suitable solvent. The dyed polymer is soluble in nonpolar solvents, and the dyes do not phase separate, even in nonsolvents for the pure dye salts. Microanalytical data on the particles and films were acquired using energy-loss spectroscopy imaging (ESI-TEM) and scanning electric potential microscopy (SEPM). The results are interpreted considering that (i) the polystyrene latex particles have a mild ionomer character, due to the charged sulfate groups arising from the polymerization initiator and bound to the chain ends; (ii) there is formation of ion pairs made out of dye cation and chain-end sulfate; (iii) the cationic dye self-associates, as evidenced by a pronounced metachromatic behavior. A nonpolar polymer can thus be made compatible with a basic dye without any special chain modification, just by using this new procedure based on dye sorption followed by diffusion.
Country: EUA
Editor: Amer Chemical Soc
Rights: fechado
Identifier DOI: 10.1021/la034258p
Date Issue: 2003
Appears in Collections:Artigos e Materiais de Revistas Científicas - Unicamp

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