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Type: Artigo de periódico
Title: On the reactivity of alpha-(triphenylphosphoranylidene)-benzylphenylketene with nitrogen compounds. Synthetic and mechanistic implications
Author: Cunha, S
Kascheres, A
Abstract: The reactivity of alpha-(triphenylphosphoranylidene)-benzylphenylketene, a stabilized phosphorus ylide derived from diphenylcyclopropenone, toward nitrogen compounds was investigated. Particularly, the reaction of diethyl azodicarboxylate with alpha-(triphenylphosphoranylidene)-benzylphenylketene provides a new route to polysubstituted N-acyl carbamates.
Subject: alpha-(triphenylphosphoranylidene)-benzylphenylketene
phosphorus ylides
acyl carbamate
Country: Brasil
Editor: Soc Brasileira Quimica
Citation: Journal Of The Brazilian Chemical Society. Soc Brasileira Quimica, v. 13, n. 5, n. 687, n. 691, 2002.
Rights: aberto
Date Issue: 2002
Appears in Collections:Unicamp - Artigos e Outros Documentos

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