Please use this identifier to cite or link to this item: http://repositorio.unicamp.br/jspui/handle/REPOSIP/68714
Type: Artigo de periódico
Title: On the mechanism of the aza-Morita-Baylis-Hillman reaction: ESI-MS interception of a unique new intermediate
Author: Regiani, T
Santos, VG
Godoi, MN
Vaz, BG
Eberlin, MN
Coelho, F
Abstract: Solutions of aza-Morita-Baylis-Hillman (aza-MBH) reactions were directly monitored by ESI(+)-MS(/MS) spectrometry to obtain information on their mechanism. A unique bis-sulfonamide intermediate was intercepted and characterized and, based on this novel species, a mechanism that rationalizes the uniqueness of aza-MBH reactions is proposed.
Country: Inglaterra
Editor: Royal Soc Chemistry
Rights: embargo
Identifier DOI: 10.1039/c1cc10678c
Date Issue: 2011
Appears in Collections:Artigos e Materiais de Revistas Científicas - Unicamp

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