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|Type:||Artigo de periódico|
|Title:||On the mechanism of the aza-Morita-Baylis-Hillman reaction: ESI-MS interception of a unique new intermediate|
|Abstract:||Solutions of aza-Morita-Baylis-Hillman (aza-MBH) reactions were directly monitored by ESI(+)-MS(/MS) spectrometry to obtain information on their mechanism. A unique bis-sulfonamide intermediate was intercepted and characterized and, based on this novel species, a mechanism that rationalizes the uniqueness of aza-MBH reactions is proposed.|
|Editor:||Royal Soc Chemistry|
|Appears in Collections:||Artigos e Materiais de Revistas Científicas - Unicamp|
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