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Type: Artigo de periódico
Title: Highly stereoselective preparation of (3R,4S)-3,4-chromanediol by deracemization of (+/-)-3-hydroxy-4-chromanone by Trichosporon cutaneum
Author: Lunardi, I
Conceicao, GJA
Moran, PJS
Rodrigues, JAR
Abstract: Deracernization of (+/-)-3-hydroxy-4-chrornan one 2 through stercoselective bioreduction to the corresponding (3R,4S)-3,4-chromanediol 3, with good to excellent enantiomeric excesses (LIP to 99%). mediated by resting cells of the yeast Trichosporon cutaneum CCT 1903, is reported. In addition, 3-hydroxychronione (7) was obtained as a secondary product. (c) 2005 Elsevier Ltd. All rights reserved.
Country: Inglaterra
Editor: Pergamon-elsevier Science Ltd
Citation: Tetrahedron-asymmetry. Pergamon-elsevier Science Ltd, v. 16, n. 15, n. 2515, n. 2519, 2005.
Rights: fechado
Identifier DOI: 10.1016/j.tetasy.2005.06.020
Date Issue: 2005
Appears in Collections:Unicamp - Artigos e Outros Documentos

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