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Type: Artigo de periódico
Title: Highly Regio- and Stereoselective Heck Reaction of Allylic Esters with Arenediazonium Salts: Application to the Synthesis of Kavalactones
Author: Moro, AV
Cardoso, FSP
Correia, CRD
Abstract: A highly efficient palladium-catalyzed Heck reaction of allylic esters with arenediazonium salts is described. The reaction proceeds under mild conditions, with excellent to total regio- and stereochemical control and with retention of the traditional leaving group. Furthermore, the generality of the present methodology is illustrated by the short total synthesis of the natural kavalactones, yangonine, (+/-)-methysticin, and (+/-)-dihydromethysticin.
Country: EUA
Editor: Amer Chemical Soc
Citation: Organic Letters. Amer Chemical Soc, v. 11, n. 16, n. 3642, n. 3645, 2009.
Rights: fechado
Identifier DOI: 10.1021/ol901416e
Date Issue: 2009
Appears in Collections:Unicamp - Artigos e Outros Documentos

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