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Type: Artigo de periódico
Title: Highly Functionalized Spirocyclohexadienones from Morita-Baylis-Hillman Adducts
Author: Pirovani, RV
Ferreira, BRV
Coelho, F
Abstract: Spirohexadienone is a structural moiety present in several biologically active natural products isolated both from terrestrial and marine natural sources. This structural moiety is commonly and strictly related to the biological properties exhibited by the natural products. We show herein that the combination of intermolecular Heck reactions with a phenolic oxidation induced by hypervalent iodine form these structural moieties from Morita-Baylis-Hillman adducts in moderate to good overall yields.
Subject: Morita-Baylis-Hillman
Heck reaction
spiro compounds
hypervalent iodine
Country: Alemanha
Editor: Georg Thieme Verlag Kg
Citation: Synlett. Georg Thieme Verlag Kg, n. 14, n. 2333, n. 2337, 2009.
Rights: embargo
Identifier DOI: 10.1055/s-0029-1217725
Date Issue: 2009
Appears in Collections:Unicamp - Artigos e Outros Documentos

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