Please use this identifier to cite or link to this item: http://repositorio.unicamp.br/jspui/handle/REPOSIP/68362
Type: Artigo de periódico
Title: High refrigerant capacity of PrNi5-xCox magnetic compounds exploiting its spin reorientation and magnetic transition over a wide temperature zone
Author: Rocco, DL
Amaral, JS
Leitao, JV
Amaral, VS
Reis, MS
Das, S
Fernandes, RP
Araujo, JP
Pereira, AM
Tavares, PB
Martins, NV
Coelho, AA
Abstract: The ferromagnetically coupled cobalt ion is observed to create a magnetocrystalline anisotropy in the PrNi5-xCox structure above a critical composition of x = 2. The competition of the anisotropy energies between Co and Pr sublattices gives rise to a spin reorientation (SR) phenomenon in PrNi5-xCox compounds at a low temperature (similar to 150 K) which is then followed by a magnetic transition at a higher temperature. Co-doping has a strong influence on the Curie temperature, changing it from similar to 60K (x = 1.95) to similar to 537K ( x = 3). The magnetic entropy change is associated with SR as well as a magnetic transition, and correspondingly a large full width at half maximum (delta T-FWHM) is obtained for this series of compounds. For example, the PrNi2.85Co2.15 compound presents delta T-FWHM = 166K at a 1 T field. This series therefore has an appreciable relative cooling power, which makes this material a suitable magnetic refrigerant over a large temperature span.
Country: Inglaterra
Editor: Iop Publishing Ltd
Rights: fechado
Identifier DOI: 10.1088/0022-3727/42/5/055002
Date Issue: 2009
Appears in Collections:Artigos e Materiais de Revistas Científicas - Unicamp

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