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Type: Artigo de periódico
Title: High 1,4-syn-induction in the addition of chiral allyltrichlorostannanes to chiral aldehydes
Author: Dias, LC
Giacomini, R
Meira, PRR
Ferreira, E
Ferreira, AA
Diaz, G
dos Santos, DR
Steil, LJ
Abstract: Chiral and achiral allyltrichlorostannanes reacted with chiral aldehydes to give the corresponding homoallylic alcohols with good to high diastereoselectivities. This approach has been applied to the synthesis of hydroxyethylene dipeptide isosteres L-682, 679, L-684,414, L-685,434 and L-685,458.
Subject: allylsilanes
chiral aldehydes
ligand exchange reactions
Country: EUA
Editor: Arkat Usa Inc
Citation: Arkivoc. Arkat Usa Inc, n. 240, n. 261, 2003.
Rights: aberto
Date Issue: 2003
Appears in Collections:Unicamp - Artigos e Outros Documentos

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