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Type: Artigo de periódico
Title: Hexaaquoaluminum(III) as an environmental friendly activator of hydrogen peroxide for the catalytic epoxidation of cis-cyclooctene
Author: Rinaldi, R
Fujiwara, FY
Schuchardt, U
Abstract: A significant effort has been done towards the development of new catalysts for the synthesis of epoxides in a more environmental friendly way. We have found that a simple hexaaquoaluminum salt (2 mol% of Al(NO3)(3) . 9H(2)O) is able to catalyze the epoxidation of cis-cyclooctene with high yields using aqueous (70 wt%) hydrogen peroxide. In THF we obtained 98% of conversion with 88% of selectivity for cyclooctene epoxide after 12 h. (C) 2004 Elsevier B.V. All rights reserved.
Subject: epoxidation
hydrogen peroxide
Country: Holanda
Editor: Elsevier Science Bv
Citation: Catalysis Communications. Elsevier Science Bv, v. 5, n. 6, n. 333, n. 337, 2004.
Rights: fechado
Identifier DOI: 10.1016/j.catcom.2004.04.003
Date Issue: 2004
Appears in Collections:Unicamp - Artigos e Outros Documentos

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