Please use this identifier to cite or link to this item: http://repositorio.unicamp.br/jspui/handle/REPOSIP/68206
Type: Artigo de periódico
Title: Heck Reaction on Morita-Baylis-Hillman Adducts: Diastereoselective Synthesis of Pyrrolizidinones and Pyrrolizidines
Author: Freire, KRD
Tormena, CF
Coelho, F
Abstract: An efficient approach to the diastereoselective synthesis of benzylidene-, benzyl-pyrrolizidinones, and pyrrolizidines is described. The sequence is based on a highly stereoselective Heck reaction between a hydroxylated pyrrolizidinone, prepared from a Morita-Baylis-Hillman adduct, and a suitable aryl halide, using Najera's oxime derived palladacycle as catalyst.
Subject: Morita-Baylis-Hillman
Heck reaction
bicyclic compounds
heterocycles
palladium
Country: Alemanha
Editor: Georg Thieme Verlag Kg
Rights: embargo
Identifier DOI: 10.1055/s-0030-1261161
Date Issue: 2011
Appears in Collections:Artigos e Materiais de Revistas Científicas - Unicamp

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