Please use this identifier to cite or link to this item: http://repositorio.unicamp.br/jspui/handle/REPOSIP/67512
Type: Artigo de periódico
Title: Obtention and characterization of poly(3-hydroxybutyricacid-co-hydroxyvaleric acid)/mcl-PHA based blends
Author: Martelli, SM
Sabirova, J
Fakhoury, FM
Dyzma, A
de Meyer, B
Soetaert, W
Abstract: The aim of this work was to evaluate the physical-chemical properties of blends of poly(3-hydroxybutyrate-co-3-hydroxyvalerate) (PHBV) and a medium-chain-length polyhydroxyalkanoate (LA). Blends were obtained by casting film-solution on leveled trays. Morphological analysis showed compatibility between the two polymers up to 5 g/100 g of LA polymer was added and phase separation in the polymeric system for compositions containing more than 5 g/100 g of LA polymer. TGA data and glass transition temperatures revealed some compatibility of the polymers. Moreover, there is a significant decrease of melting temperature and elasticity modulus for PHBV LA blends with composition. Films containing 5 g/100 g of LA polymer showed an improvement of 50% in elongation to break (SB) when compared with pure PHBV. For other samples the SB decreased most likely due to the lack of adhesion between the two polymeric phases. Crown Copyright (C) 2012 Published by Elsevier Ltd. All rights reserved.
Subject: PHBV
mcl-PHA
Biodegradable film
Miscibility
Country: Holanda
Editor: Elsevier Science Bv
Rights: fechado
Identifier DOI: 10.1016/j.lwt.2012.01.036
Date Issue: 2012
Appears in Collections:Unicamp - Artigos e Outros Documentos

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