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Type: Artigo de periódico
Title: Exploratory analysis of simultaneous degradation of anthocyanins in the calyces of flowers of the Hibiscus sabdariffa species by PARAFAC model
Author: Marco, PH
Levi, MAB
Scarminio, IS
Poppi, RJ
Trevisan, MG
Abstract: A three-way resolution method based on PARAFAC model was applied for the UV-Vis spectra to study the simultaneous degradation of anthocyanins extracted from fresh calyces of flowers of the Hibiscus sabdariffa. This methodology was used to resolve a chemical system, for which there was no a priori information about the composition or the pure spectra, a so-called black system. In the pH range from 1 to 13, seven species were identified: flavylium cation, carbinol, quinoidal base, E- and Z-chalcones and E- and Z-ionized chalcones. The concentration changes were determined as functions of pH at different wavelengths. The pK values for the acidity constants as well as tautomeric constant were estimated as 2.70, 3.54 and 0.14, respectively. The spectral profiles recovered by the chemometric methods are in excellent agreement with bands of experimental spectra reported in the literature for the species measured at specific pH values.
Country: Japão
Editor: Japan Soc Analytical Chemistry
Citation: Analytical Sciences. Japan Soc Analytical Chemistry, v. 21, n. 12, n. 1523, n. 1527, 2005.
Rights: fechado
Identifier DOI: 10.2116/analsci.21.1523
Date Issue: 2005
Appears in Collections:Unicamp - Artigos e Outros Documentos

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