Please use this identifier to cite or link to this item: http://repositorio.unicamp.br/jspui/handle/REPOSIP/66398
Type: Artigo de periódico
Title: Experimental study of methane and carbon dioxide solubility in 1,4 butylene glycol at pressures up to 11 MPa and temperatures ranging from 303 to 423 K
Author: Galvao, AC
Francesconi, AZ
Abstract: This work reports solubility data of methane and carbon dioxide in 1,41 butylene glycol and the Henry's law constant of each solute in the studied solvent at saturation pressure. The measurements were performed at 303, 323, 373, 398 and 423.15 K and pressures up to 3.8 MPa for mixtures containing carbon dioxide and pressures up to 10.9 MPa for mixtures containing methane. The experiments were performed in an autoclave type phase equilibrium apparatus using a technique based on the total pressure method (synthetic method). All investigated systems show an increase of gas solubility with the increase of pressure. A decrease of carbon dioxide solubility with the increase of temperature and an increase of methane solubility with the increase of temperature were observed. From the variation of solubility with temperature, the partial molar enthalpy and entropy change of each mixture were calculated. (C) 2009 Elsevier B.V. All rights reserved.
Subject: Gas solubility
Henry's constant
Methane
Carbon dioxide
1,4 butylene glycol
Country: Holanda
Editor: Elsevier Science Bv
Rights: fechado
Identifier DOI: 10.1016/j.supflu.2009.08.012
Date Issue: 2009
Appears in Collections:Artigos e Materiais de Revistas Científicas - Unicamp

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