Please use this identifier to cite or link to this item: http://repositorio.unicamp.br/jspui/handle/REPOSIP/66162
Type: Artigo de periódico
Title: Evolution of oxidation in soybean oil and its biodiesel under the conditions of the oxidation stability test
Author: Pereira, GG
Marmesat, S
Barrera-Arellano, D
Dobarganes, MC
Abstract: The objective of this study was to know the evolution of the oxidation of soybean oil and biodiesel under the conditions of the oxidation stability test (110 degrees C) using the Rancimat apparatus. Samples were analyzed at different periods of time until the end of the induction period. The analytical determinations related to the changes in oxidation include peroxide value, anisidine value, natural tocopherols and polar compounds. Acid value, kinematic viscosity, polymers and ester content were also analyzed because of their relevance in the evaluation of biodiesel quality. Results showed that only peroxide value and the group of polar compounds including hydroperoxides, i.e. oxidized monomeric TAG in the oil and oxidized monomeric FAME in the biodiesel increased significantly during the early oxidation stage. The end of the induction period was marked by a rapid increase in polymerization compounds and the exhaustion of tocopherols. Significant changes in acid value, viscosity and ester content were only observed after the end of the induction period.
Subject: Acid value
Anisidine value
Biodiesel
Oxidation
Peroxide value
Polar compounds
Soybean oil
Tocopherols
Viscosity
Country: Espanha
Editor: Inst Grasa Sus Derivados
Citation: Grasas Y Aceites. Inst Grasa Sus Derivados, v. 64, n. 5, n. 482, n. 488, 2013.
Rights: fechado
Identifier DOI: 10.3989/gya.036913
Date Issue: 2013
Appears in Collections:Unicamp - Artigos e Outros Documentos

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