Please use this identifier to cite or link to this item: http://repositorio.unicamp.br/jspui/handle/REPOSIP/65807
Type: Artigo de periódico
Title: Evaluation of DMIT [4,5-Dimercapto-1,3-Dithyol-2-Thionate] as chelating agent in a cloud point extraction procedure for Pb2+ determination in water samples
Author: Godoy, NV
Somera, BF
Barreto, WJ
Barreto, SRG
Tarley, CRT
Abstract: The present study proposes a new method for cloud point preconcentration of Pb2+ ions based on complex formed with [4,5-dimercapto-1,3-dithyol-2-thionate] and posterior determination by flame atomic absorption spectrometry (FAAS). The preconcentration of Pb2+ was carried at pH 5.0 under following conditions: time and temperature of batch at 15 min. and 70 degrees C, respectively, 0.1% (v/v) Triton X-114, 0.003 mol L-1 acetate/acetic acid buffer solution, 1.0 x 10(-5) mol L-1 DMIT and 0.5% (m/v) NaCl. Under the best analytical conditions the method provided a limit of detection of 2.85 mu g L-1 by preconcentrating 10.0 mL of sample and calibration curve ranging from 0 up to 650 mu g L-1 (r = 0.99945). The applicability of proposed method for Pb2+ determination in natural waters without interferences was checked through addition/recovery tests.
Subject: DMIT [4,5-dimercapto-1,3-dithyol-2-thionate]
cloud point
lead
FAAS
Country: Brasil
Editor: Univ Estadual Maringa, Pro-reitoria Pesquisa Pos-graduacao
Rights: aberto
Identifier DOI: 10.4025/actascitechnol.v35i2.18076
Date Issue: 2013
Appears in Collections:Unicamp - Artigos e Outros Documentos

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