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Type: Artigo de periódico
Title: Enhancements of enantio and diastereoselectivities in reduction of (Z)-3-halo-4-phenyl-3-buten-2-one mediated by microorganisms in ionic liquid/water biphasic system
Author: Zampieri, DS
de Paula, BRS
Zampieri, LA
Vale, JA
Rodrigues, JAR
Moran, PJS
Abstract: Reductions of (Z)-C6H5CH=CXC(=O)CH3 (X=Cl, Br) mediated by Saccharomyces cerevisiae, Candida albicans, Rhodotorula glutinis, Geotrichum candidum and Micrococcus luteus gave the corresponding halohydrins through consecutive reduction reactions of C=C and C=O bonds. In general, the reactions performed in the biphasic system water/[(bmim)PF6] gave better diastereoselectivity and enantioselectivity than in pure water. (C) 2012 Elsevier B.V. All rights reserved.
Subject: Halohydrins
Saccharomyces cerevisiae
Ionic liquid
Country: Holanda
Editor: Elsevier Science Bv
Citation: Journal Of Molecular Catalysis B-enzymatic. Elsevier Science Bv, v. 85-86, n. 61, n. 64, 2013.
Rights: fechado
Identifier DOI: 10.1016/j.molcatb.2012.08.005
Date Issue: 2013
Appears in Collections:Unicamp - Artigos e Outros Documentos

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