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Type: Artigo de periódico
Title: Enantioselective synthesis of alpha-hydroxysilanes by bioreduction of aroyltrimethylsilanes
Author: Patrocinio, AF
Correa, IR
Moran, PJS
Abstract: Aromatic acylsilanes [Ar-CO-SiMe3; Ar = C6H5, 4-ClC6H4, 2-, 3- and 4-OMeC6H4, 3,4-(OMe)(2)C6H5 and 3,4-OCH2OC6H3] were reduced by baker's yeast to optically active alpha-silyl alcohols in 20-70% yield and 43-88% ee. Comments are made on the influence of silicon in this bioreduction reaction.
Country: Inglaterra
Editor: Royal Soc Chemistry
Citation: Journal Of The Chemical Society-perkin Transactions 1. Royal Soc Chemistry, n. 21, n. 3133, n. 3137, 1999.
Rights: aberto
Identifier DOI: 10.1039/a906335h
Date Issue: 1999
Appears in Collections:Unicamp - Artigos e Outros Documentos

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