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|Type:||Artigo de periódico|
|Title:||Elemental mapping in natural rubber latex films by electron energy loss spectroscopy associated with transmission. electron microscopy|
|Abstract:||Element distribution maps from Hevea brasiliensis natural rubber latex thin films were obtained, by electron energy-loss spectroscopic imaging in a low-energy (80 kV) transmission electron microscope. C, N, O, P, Na, Ca, Mg, Al, Si, and S maps are presented for latex fractionated by centrifugation, either followed by dialysis or not. Most elements forming non-carbon compounds are concentrated in small, electron-dense spots surrounded by a carbon-rich matrix of polymer, thus showing that the rubber is filled with small particles compatible with the polyisoprene matrix. Ca distribution is unique, since it closely parallels the C distribution, evidencing an important role for -COO--Ca2+-COO- ionic bridges in the structure of natural rubber.|
|Editor:||Amer Chemical Soc|
|Citation:||Analytical Chemistry. Amer Chemical Soc, v. 74, n. 11, n. 2541, n. 2546, 2002.|
|Appears in Collections:||Unicamp - Artigos e Outros Documentos|
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