Please use this identifier to cite or link to this item: http://repositorio.unicamp.br/jspui/handle/REPOSIP/64618
Type: Artigo de periódico
Title: Electrospray ionization mass spectrometry fingerprinting of perfumes: rapid classification and counterfeit detection
Author: Marques, LD
Catharino, RR
Bruns, RE
Eberlin, MN
Abstract: A fast procedure to classify perfumes and identify counterfeit samples is described. Dilution of a few mu L of the sample in a 1:1 methanol/water solution is followed by detection of its major polar components via direct infusion electrospray ionization mass spectrometry (ESI-MS) in the positive ion mode. As proof-of-principle cases, three famous brands of perfumes were used. The ESI(+)-MS fingerprints of authentic samples were very characteristic, showing distinctive sets of polar markers for each sample. Principal component analysis (PCA) placed samples of the three perfume brands in well-defined groups. Counterfeit samples were also clearly detected owing to contrasting ESI-MS fingerprints, with PCA placing these samples far away from the authentic samples. Copyright (c) 2006 John Wiley & Sons, Ltd.
Country: Inglaterra
Editor: John Wiley & Sons Ltd
Rights: fechado
Identifier DOI: 10.1002/rcm.2779
Date Issue: 2006
Appears in Collections:Unicamp - Artigos e Outros Documentos

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