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Type: Artigo de periódico
Title: Electronic spectra of some Ni2+ octahedral complexes: A practical introduction to the crystal field theory in the undergraduate course.
Author: Gushikem, Y
Abstract: ELECTRONIC SPECTRA OF SOME Ni2+ OCTAHEDRAL COMPLEXES: A PRACTICAL INTRODUCTION TO THE CRYSTAL FIELD THEORY IN THE UNDERGRADUATE COURSE. The experiment introduces the undergraduate students to the crystal field theory. The electronic spectra of the octahedral complexes of [Ni(L)(n)](2+) (L = H2O dmso, NH3 and en) obtained in the experiment are used to calculate 10Dq and B parameters. The experiment shows how the parameters can be calculated and correlated with the nature of the ligands and the field intensities produced.
Subject: Ni(II) octahedral complexes
electronic spectra
crystal field parameters
Country: Brasil
Editor: Soc Brasileira Quimica
Citation: Quimica Nova. Soc Brasileira Quimica, v. 28, n. 1, n. 153, n. 156, 2005.
Rights: aberto
Identifier DOI: 10.1590/S0100-40422005000100027
Date Issue: 2005
Appears in Collections:Unicamp - Artigos e Outros Documentos

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