Please use this identifier to cite or link to this item: http://repositorio.unicamp.br/jspui/handle/REPOSIP/63101
Full metadata record
DC FieldValueLanguage
dc.contributor.CRUESPUniversidade Estadual de Campinaspt_BR
dc.typeArtigo de periódicopt_BR
dc.titleChiral allylsilane additions to chiral alpha-substituted aldehydespt_BR
dc.contributor.authorDias, LCpt_BR
dc.contributor.authorGiacomini, Rpt_BR
unicamp.author.emailldias@iqm.unicamp.brpt_BR
unicamp.authorUniv Estadual Campinas, Inst Quim, UNICAMP, BR-13083970 Campinas, SP, Brazilpt_BR
dc.subjectchiral allylsilanept_BR
dc.subjecttransmetallationpt_BR
dc.subject1,4-asymmetric inductionpt_BR
dc.subjectpolyacetate derived natural productspt_BR
dc.subject.wosEsterspt_BR
dc.subject.wosInductionpt_BR
dc.description.abstractChiral allylsilane 3 reacted with chiral alpha-methyl-beta-siloxy-aldehydes to afford the corresponding 1,4-syn-products with good diastereoselectivities independent of the absolute stereochemistry of these aldehydes. The best selectivities are observed when the reactions are carried out by transmetallation of the allylsilane 3 using Tin (IV) Chloride in CH2Cl2, at -78 degrees C, before addition of the aldehydes.pt
dc.relation.ispartofJournal Of The Brazilian Chemical Societypt_BR
dc.relation.ispartofabbreviationJ. Braz. Chem. Soc.pt_BR
dc.publisher.citySao Paulopt_BR
dc.publisher.countryBrasilpt_BR
dc.publisherSoc Brasileira Quimicapt_BR
dc.date.issued1998pt_BR
dc.date.monthofcirculationJUL-AUGpt_BR
dc.identifier.citationJournal Of The Brazilian Chemical Society. Soc Brasileira Quimica, v. 9, n. 4, n. 357, n. 369, 1998.pt_BR
dc.language.isoenpt_BR
dc.description.volume9pt_BR
dc.description.issuenumber4pt_BR
dc.description.firstpage357pt_BR
dc.description.lastpage369pt_BR
dc.rightsabertopt_BR
dc.sourceWeb of Sciencept_BR
dc.identifier.issn0103-5053pt_BR
dc.identifier.wosidWOS:000076382300008pt_BR
dc.identifier.doi10.1590/S0103-50531998000400008pt_BR
dc.date.available2014-12-02T16:29:04Z
dc.date.available2015-11-26T16:46:37Z-
dc.date.accessioned2014-12-02T16:29:04Z
dc.date.accessioned2015-11-26T16:46:37Z-
dc.description.provenanceMade available in DSpace on 2014-12-02T16:29:04Z (GMT). No. of bitstreams: 1 WOS000076382300008.pdf: 894505 bytes, checksum: b501d4a430696c462769da057453b7bf (MD5) Previous issue date: 1998en
dc.description.provenanceMade available in DSpace on 2015-11-26T16:46:37Z (GMT). No. of bitstreams: 2 WOS000076382300008.pdf: 894505 bytes, checksum: b501d4a430696c462769da057453b7bf (MD5) WOS000076382300008.pdf.txt: 55939 bytes, checksum: d139043cfad6dac2a639e6df0df26046 (MD5) Previous issue date: 1998en
dc.identifier.urihttp://www.repositorio.unicamp.br/jspui/handle/REPOSIP/63101pt_BR
dc.identifier.urihttp://www.repositorio.unicamp.br/handle/REPOSIP/63101
dc.identifier.urihttp://repositorio.unicamp.br/jspui/handle/REPOSIP/63101-
Appears in Collections:Unicamp - Artigos e Outros Documentos

Files in This Item:
File Description SizeFormat 
WOS000076382300008.pdf873.54 kBAdobe PDFView/Open


Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.