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Type: Artigo de periódico
Title: Direct conversion of acylsilanes to esters mediated by iron (III) and nitrate ions
Author: Patrocinio, AF
Moran, PJS
Abstract: Acylsilanes, RC(O)SiMe3 (R = C6H5, p-MeOC6H4 and C5H11), can be converted into their corresponding carboxylic acids, when water is used as solvent, and esters when alcohol is used as solvent. This oxidation is mediated by iron (III) ions in 20-24 h or nitric acid diluted in alcohol in 2-10 h at room temperature.
Country: EUA
Editor: Marcel Dekker Inc
Rights: fechado
Identifier DOI: 10.1080/00397910008087169
Date Issue: 2000
Appears in Collections:Unicamp - Artigos e Outros Documentos

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