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|Type:||Artigo de periódico|
|Title:||NUCLEOPHILIC INTERCEPTION OF THE GAMMA,DELTA-ACETYLENIC ALPHA,BETA-OLEFINIC ALDEHYDE INTERMEDIATE FORMED FROM FURIL MONOTOSYLHYDRAZONE|
|Abstract:||The reaction of furil monotosylhydrazone (1) with nucleophiles under basic conditions led to the formation of 5-(2-furoylmethylene)-2-pyrrolidinones 3 when amines and hydrazine hydrate were used. Treatment with methylhydrazine led td production of 1-methyl-6-(2-furoylmethylene)pyridazine (4) while treatment with phenylhydrazine and 4-nitrophenylhydrazine produced 1-(2-furoyl)-6-anilino-6-azafulvene (5a) and 1-(2-furoyl)-6-(4-nitroanilino)-6-azafulvene (5b), respectively. All products suggest interception of the gamma,delta-acetylenic alpha,beta-olefinic aldehyde intermediate 2 formed via the unstable 1,2-difuryldiazoethanone.|
|Editor:||Amer Chemical Soc|
|Appears in Collections:||Unicamp - Artigos e Outros Documentos|
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