Please use this identifier to cite or link to this item: http://repositorio.unicamp.br/jspui/handle/REPOSIP/62133
Type: Artigo de periódico
Title: NOVEL ALKYNE AND PHOSPHAALKYNE COUPLING ON AN IR-4 CLUSTER - SYNTHESIS AND MOLECULAR-STRUCTURE OF [IR-4(MU-CO)(CO)(7)(MU(4)-ETA(3)-PH(2)PC(H)C(PH)PCBU(T))(MU-PPH(2))]
Author: BENVENUTTI, MHA
HITCHCOCK, PB
NIXON, JF
VARGAS, MD
Abstract: The cluster compound [(mu-H)Ir-4(CO)g(Ph(2)PCCPh)(mu-PPh(2))] 1 reacts with the phosphaalkyne Bu(t)CP to yield [Ir-4(mu-Co)(Co)(7){mu(4)-eta(3)-Ph(2)PC(H)C(Ph)PCBu(t)}(mu-PPh(2))] 3, containing the novel 2-phosphabutadienylphosphine fragment as a result of the coupling of Bu(t)CP with the diphenylphosphinoalkyne ligand and incorporation of the cluster bound H atom.
Country: Inglaterra
Editor: Royal Soc Chemistry
Rights: aberto
Identifier DOI: 10.1039/c39940001869
Date Issue: 1994
Appears in Collections:Unicamp - Artigos e Outros Documentos

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