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|Type:||Artigo de periódico|
|Title:||Differential oxidation of endocyclic enecarbamates. Synthesis of cyclic beta-hydroxy-alpha-amino acids.|
|Abstract:||The differential oxidation of five and six-membered endocyclic enecarbamates was investigated employing m-CPBA, DMD, as well as enantioselective protocols such as the Kochi-Jacobsen-Katsuki's epoxidation and the Sharpless dihydroxylation. By this strategy the syntheses of beta-hydroxyprolines and beta-hydroxypipecolic acids were accomplished. X-Ray crystallographic analysis of the trans-beta-hydroxypipecolic acid was instrumental to solve structural assignment conflicts. (C) 1998 Published by Elsevier Science Ltd. All rights reserved.|
|Editor:||Pergamon-elsevier Science Ltd|
|Appears in Collections:||Unicamp - Artigos e Outros Documentos|
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