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Type: Artigo de periódico
Title: Diastereo- and enantioselective synthesis of a conagenin skeletal amide moiety
Author: Augusto, J
Rodrigues, R
Moran, PJS
Milagre, CDF
Ursini, CV
Abstract: A synthetic study was carried out to obtain epimers of a protected 2,4-dihydroxy-3-methylpentanoic ester 9, which is a central building block of the immunomodulator (+)-conagenin 1. The configuration of the three contiguous stereogenic centers was determined by NMR measurements and comparison with the stereogenic centers of lactone 10. (C) 2004 Elsevier Ltd. All rights reserved.
Subject: conagenin
beta-methylene-alpha-keto ester
Country: Inglaterra
Editor: Pergamon-elsevier Science Ltd
Rights: fechado
Identifier DOI: 10.1016/j.tetlet.2004.03.062
Date Issue: 2004
Appears in Collections:Unicamp - Artigos e Outros Documentos

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