Please use this identifier to cite or link to this item: http://repositorio.unicamp.br/jspui/handle/REPOSIP/60626
Type: Artigo de periódico
Title: Investigation of reaction mechanisms by electrospray ionization mass spectrometry: characterization of intermediates in the degradation of phenol by a novel iron/magnetite/hydrogen peroxide heterogeneous oxidation system
Author: Moura, FCC
Araujo, MH
Dalmazio, I
Alves, TMA
Santos, LS
Eberlin, MN
Augusti, R
Lago, RM
Abstract: Electrospray ionization (ESI) mass spectrometry (MS) and tandem mass spectrometry (MS/MS) were used to monitor the oxidation of phenol by a novel heterogeneous Fenton system based on a Fe-0/Fe3O4 composite and H2O2. On-line ESI-MS(/MS) shows that this heterogeneous system promotes prompt oxidation of phenol to hydroquinone, which is subsequently oxidized to quinone, other cyclic poly-hydroxylated intermediates and an acyclic carboxylic acid. A peroxide-type intermediate, probably formed via an electrophilic attack of HOO. on the phenol ring, was also intercepted and characterized. ESI-MS(/MS) monitoring of the oxidation of two other model aromatic compounds, benzene and chlorobenzene, indicates the participation of analogous intermediates. These results suggest that oxidation by the heterogeneous system is promoted by highly reactive HO. and HOO. radicals generated from H2O2 on the surface of the Fe-0/Fe3O4 composite via a classical Fenton-like mechanism. Copyright (c) 2006 John Wiley & Sons, Ltd.
Country: Inglaterra
Editor: John Wiley & Sons Ltd
Rights: fechado
Identifier DOI: 10.1002/rcm.2523
Date Issue: 2006
Appears in Collections:Unicamp - Artigos e Outros Documentos

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