Please use this identifier to cite or link to this item: http://repositorio.unicamp.br/jspui/handle/REPOSIP/60555
Type: Artigo de periódico
Title: INTRAZEOLITE METAL-CARBONYL KINETICS - (CO)-C-12 SUBSTITUTION IN MO(12CO)6-NA56Y BY PME3 AND (CO)-C-13
Author: OZIN, GA
OZKAR, S
PASTORE, HO
POE, AJ
VICHI, EJS
Abstract: The first kinetic study is reported for archetypical substitution reactions of PMe3 and 13CO with the well defined intrazeolite system, Mo(12CO)6-Na56Y, for which excellent isosbestic points and first order behaviour are obtained, the activation parameters indicate a highly ordered 'supramolecular' transition state consisting of activated Mo(12CO)6 and PMe3 or 13CO all anchored to the Na+ ions in the alpha-cage of the host lattice.
Country: Inglaterra
Editor: Royal Soc Chemistry
Rights: aberto
Identifier DOI: 10.1039/c39910000141
Date Issue: 1991
Appears in Collections:Unicamp - Artigos e Outros Documentos

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