Please use this identifier to cite or link to this item: http://repositorio.unicamp.br/jspui/handle/REPOSIP/60481
Type: Artigo de periódico
Title: Interplay between crystallization and particle growth during the isothermal annealing of colloidal iron oxide nanoparticles
Author: Haddad, PS
Rocha, TR
Souza, EA
Martins, TM
Knobel, M
Zanchet, D
Abstract: The relationship between crystallization and growth of colloidal iron oxide nanoparticles during isothermal annealing was addressed in this work. The structural, morphological and chemical modifications of the nanoparticles during thermal treatments were followed by combination of electron microscopy, X-ray diffraction and spectroscopic methods. The initially monodisperse spherical nanoparticles with amorphous and partially oxidized structure evolved during the treatments, depending on the temperature and treatment time. Core-void-shell nanoparticles or single crystal nanoparticles and hollow polycrystalline nanoparticles, both with well defined Fe3O4 oxide phase, are formed depending on the conditions. This evolution was interpreted as a result of the Kirkendall effect associated to mass redistribution and fragmentation of the nanoparticles, bringing new information about the effect of post-synthesis treatments on the crystallinity and morphology of colloidal nanoparticles. (C) 2009 Elsevier Inc. All rights reserved.
Subject: Iron oxide nanoparticles
Temperature
Kirkendall effect
TEM
Thermal treatment
Structure
Morphology
Ostwald ripening mechanism
Polycrystalline
Country: EUA
Editor: Academic Press Inc Elsevier Science
Rights: fechado
Identifier DOI: 10.1016/j.jcis.2009.07.068
Date Issue: 2009
Appears in Collections:Unicamp - Artigos e Outros Documentos

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