Please use this identifier to cite or link to this item: http://repositorio.unicamp.br/jspui/handle/REPOSIP/59003
Type: Artigo de periódico
Title: Palladium, palladium-tin, and palladium-silver catalysts in the selective hydrogenation of hexadienes: TPR, Mossbauer, and infrared studies of adsorbed CO
Author: Sales, EA
Jove, J
Mendes, MD
Bozon-Verduraz, F
Abstract: Alumina-supported Pd-Sn catalysts prepared by successive impregnation of the precursors, calcination, and reduction contain SnO2 and SnAl2O5, Pd-Sn solid solutions, and intermetallic phases Pd2Sn and Pd3Sn. The formation of Pd3Sn is favored not only by lowering the Sn/Pd ratio but also by introducing tin through ethanolic impregnation. The dilution of surface Pd atoms is confirmed by infrared spectroscopy of adsorbed CO: when the Sn/Pd ratio increases, the linear/bridged intensity ratio increases and the dipole-dipole interactions decrease. TPR experiments show the influence of the support acidity and of the preparation procedure on the reducibility of the various Pd-Sn and Pd-Ag species; in the case of Pd-Ag catalysts, the presence of silver postpones the reduction of PdO in calcined samples. (C) 2000 Academic Press.
Subject: Pd catalysts
Pd-Sn catalysts
Pd-Ag catalysts
Mossbauer spectroscopy
CO adsorption
FTIR spectroscopy
Pd-Sn compounds
Country: EUA
Editor: Academic Press Inc
Rights: fechado
Identifier DOI: 10.1006/jcat.2000.2967
Date Issue: 2000
Appears in Collections:Unicamp - Artigos e Outros Documentos

Files in This Item:
File Description SizeFormat 
WOS000089835100011.pdf166.27 kBAdobe PDFView/Open


Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.