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|Type:||Artigo de periódico|
|Title:||REACTION OF ENAMINOTHIONES WITH DIPHENYLCYCLOPROPENONE - SYNTHESIS OF 4,5-DIMETHYLENECYCLOPENTENONE DERIVATIVES|
|Abstract:||Diphenylcyclopropenone (1) reacts with enaminothiones 2 to afford 4,5-dimethylenecyclopentenone derivatives 3. The results of AM1 calculations performed on both geometrically optimized 2a and the oxygen analog in the Z,s-cis-configuration favor a mechanism in which the sulfur atom of 2 acts as a nucleophile at the phenyl-C of 1.|
|Editor:||Amer Chemical Soc|
|Appears in Collections:||Unicamp - Artigos e Outros Documentos|
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