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Type: Artigo de periódico
Title: Thermochemistry of Morpholine Adducts of Some Bivalent Transition Metal Bromides
Author: Dunstan, PO
Abstract: The adducts [MBr(2)(morph)(n)] (where M is Mn(II), Fe(H), Co(II), Ni(II), Cu(II), or Zn(II), morph is morpholine, and n = 1.5, 2, or 3) were synthesized and characterized by melting points, elemental analysis, thermal analysis, and electronic and IR spectroscopy. From calorimetric studies in solution, the standard enthalpies of formation of the adducts and several thermochemmical parameters were determined. The mean standard enthalpies of the metal-nitrogen bond were calculated.
Country: EUA
Editor: Amer Chemical Soc
Rights: fechado
Identifier DOI: 10.1021/je8006315
Date Issue: 2009
Appears in Collections:Unicamp - Artigos e Outros Documentos

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