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Type: Artigo de periódico
Title: Thermochemistry of adducts of bis(2,4-pentanedionato)zinc with heterocyclic amines
Author: Dunstan, PO
Abstract: The adducts Zn(AcAc)(2). nL [where L = piperazine (pipz), morpholine (morph), piperidine (pipd), pyridine (py), 3-methylpyridine (beta-pico), 4-methylpyridine (gamma-pico), 3-cyanopyridine (3-cyanopy), 4-cyanopyridine (4-cyanopy), 2,2'-bipyridine (bipy), or quinoline (quin); n = 1 or 3/2; AcAc = acetylacetonate] were synthesized and characterized by melting points, elemental analysis, thermal studies, and infrared spectroscopy. From calorimetric studies in solution, the mean standard enthalpies of the zinc-nitrogen bonds were determined.
Country: EUA
Editor: Amer Chemical Soc
Rights: fechado
Identifier DOI: 10.1021/je980113m
Date Issue: 1999
Appears in Collections:Unicamp - Artigos e Outros Documentos

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