Please use this identifier to cite or link to this item: http://repositorio.unicamp.br/jspui/handle/REPOSIP/58082
Type: Artigo de periódico
Title: THERMOCHEMISTRY OF ADDUCTS OF BIDENTATE N-LIGANDS AND O-LIGANDS WITH ARSENIC TRIHALIDES
Author: DUNSTAN, PO
Abstract: The adducts AsX3 . nL (where L is 2,2'-bipyridine (Bipy) or 2,2'-bipyridine N,N'-dioxide (BipyO2), X is Cl, Br or I and n is 1, 1.5 or 2) have been synthesized and characterized by melting points, elemental analysis, thermal studies and infrared spectroscopy. By means of calorimetric measurements in solution, the following thermochemical parameters have been determined: the standard enthalpies for the Lewis acid/base reaction (DELTA(r)H(PHI)), the standard enthalpies of formation (DELTA(f)H(PHI)), the standard enthalpies of decomposition (DELTA(D)H(PHI)), the lattice standard enthalpies (DELTA(M)H(PHI)) and the enthalpies of the Lewis acid/base reactions in the gaseous phase (DELTA(r)H(PHI)(g)). The mean standard enthalpies of arsenic-nitrogen and arsenic-oxygen bonds have been estimated.
Country: Holanda
Editor: Elsevier Science Bv
Rights: fechado
Identifier DOI: 10.1016/0040-6031(94)87031-4
Date Issue: 1994
Appears in Collections:Unicamp - Artigos e Outros Documentos

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