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Type: Artigo de periódico
Title: Thermochemistry of 3-Cyanopyridine Adducts of Some Bivalent Transition Metal Bromides
Author: Dunstan, PO
Khan, AM
Abstract: The adducts [MBr2(3-cyanopy)(n)] (where M = Mn(II), Fe(II), Co(II), Ni(II), Cu(II), or Zn(II); 3-cyanopy = 3-cyanopyridine; n = 4 or 2) were synthesized and characterized by melting points, elemental analysis, thermal studies, and IR and electronic spectroscopy. From calorimetric studies in solution, their standard enthalpies of formation and several other thermochemical parameters have been determined. The mean standard enthalpies of the metal-nitrogen bonds were calculated as well as the enthalpies of the adduct formation in the gaseous phase.
Country: EUA
Editor: Amer Chemical Soc
Rights: fechado
Identifier DOI: 10.1021/je2012617
Date Issue: 2012
Appears in Collections:Unicamp - Artigos e Outros Documentos

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