Please use this identifier to cite or link to this item: http://repositorio.unicamp.br/jspui/handle/REPOSIP/57910
Type: Artigo de periódico
Title: Theoretical studies of the asymmetric alkylation reaction on chiral enamines
Author: Burtoloso, ACB
Albuquerque, MG
Aguiar, LCD
Abstract: Semi-empirical calculations on the asymmetric alkylation of beta-ketoesters described by Koga and co-workers were carried out with the use of the MNDO semi-empirical method. This reaction is dependent on the kind of solvent used as additive for the generation of the asymmetric center with chirality control. Investigations were carried out to test how different types of additives, such as HMPA and THF, affect the establishment of this stereogenic center. (c) 2004 Elsevier B.V. All rights reserved.
Subject: chiral enamine
alkylation reaction
beta-ketoesters
HMPA
THF
Country: Holanda
Editor: Elsevier Science Bv
Rights: fechado
Identifier DOI: 10.1016/j.theochem.2004.09.060
Date Issue: 2005
Appears in Collections:Unicamp - Artigos e Outros Documentos

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