Please use this identifier to cite or link to this item: http://repositorio.unicamp.br/jspui/handle/REPOSIP/57388
Type: Artigo de periódico
Title: Cross sections and asymmetry parameters for photoionization of CH3F in the VUV region
Author: dos Santos, AS
Machado, LE
Lee, MT
Brescansin, LM
Lucchese, RR
Abstract: Calculated cross sections and asymmetry parameters for photoionization of the three outermost valence orbitals of CH3F for photon energies from near threshold to 50 eV are reported. The photoelectron continuum orbitals are obtained using the Schwinger variational method at the level of static-exchange plus correlation potential. Our results are compared with other theoretical and experimental results showing a good quantitative agreement. Correlation effects do not significantly affect the computed total cross sections and photoelectron asymmetry parameters. The broader structure that appears in the experimental cross section are well described. However, the narrow resonant features near threshold are not found in the present one-electron treatment of the photoionization process. (c) 2009 Elsevier B.V. All rights reserved.
Subject: Molecular photoionization
Country: Holanda
Editor: Elsevier Science Bv
Rights: fechado
Identifier DOI: 10.1016/j.chemphys.2008.12.028
Date Issue: 2009
Appears in Collections:Unicamp - Artigos e Outros Documentos

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