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Type: Artigo de periódico
Title: Conjugate reduction of alpha,beta-unsaturated carbonyl compounds. Selective inhibition of benzyl ether hydrogenolysis by NH4OH/MeOH
Author: Dias, LC
Campano, PL
Abstract: A series of alpha,beta-unsaturated alkyl and aryl ketones, esters and N-methoxy-N-methyl-amides (Weinreb amides) containing an O-benzyl protecting group undergo conjugate reduction by H-2/Pd/C in the presence of 2N NH4OH/MeOH at room temperature and ordinary pressure leaving the benzyl group intact.
Subject: conjugate reduction
inhibition of benzyl ether hydrogenolysis
chemoselective reduction of alpha,beta-unsaturated compounds
selective catalytic hydrogenation
Country: Brasil
Editor: Soc Brasileira Quimica
Rights: aberto
Identifier DOI: 10.1590/S0103-50531998000100017
Date Issue: 1998
Appears in Collections:Artigos e Materiais de Revistas Científicas - Unicamp

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