Please use this identifier to cite or link to this item: http://repositorio.unicamp.br/jspui/handle/REPOSIP/56116
Type: Artigo de periódico
Title: CLOUD POINT EXTRACTION/PRECONCENTRATION OF COPPER IONS EXPLOITING THE FORMATION OF COMPLEXES WITH DMIT [4,5-DIMERCAPTO-1,3-DITHYOL-2-THIONATE]
Author: Somera, BF
de Oliveira, FM
Barreto, WJ
Barreto, SRG
Tarley, CRT
Abstract: CLOUD POINT EXTRACTION/PRECONCENTRATION OF COPPER IONS EXPLOITING THE FORMATION OF COMPLEXES WITH DMIT [4,5-DIMERCAPTO-1,3-DITHYOL-2-THIONATE]. The present study proposes a method for cloud point preconcentration of copper ions at pH 2.0 based on complexes formed with [4,5-dimercapto-1,3-dithyol-2-thionate] and subsequent determination by flame atomic absorption spectrometry (FAAS). Under optimal analytical conditions, the method provided limits of detection of 0.84 and 0.45 mu g L-1, by preconcentrating 12.0 and 24.0 mL of sample, respectively. The method was applied for copper determination in water samples, synthetic saliva, guarana powder, tea samples and soft drinks and the accuracy was assessed by analyzing the certified reference materials Dogfish Liver (DOLT-4) and Lobster Hepatopancreas (TORT-2).
Subject: cloud point preconcentration
copper
DMIT [4,5-dimercapto-1,3-dithyol-2-thionate]
Country: Brasil
Editor: Soc Brasileira Quimica
Rights: aberto
Date Issue: 2012
Appears in Collections:Unicamp - Artigos e Outros Documentos

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