Please use this identifier to cite or link to this item: http://repositorio.unicamp.br/jspui/handle/REPOSIP/55769
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dc.contributor.CRUESPUniversidade Estadual de Campinaspt_BR
dc.typeArtigo de periódicopt_BR
dc.titleBlends of Soybean Biodiesel with Petrodiesel: Direct Quantitation via Mass Spectrometrypt_BR
dc.contributor.authorAbdelnur, PVpt_BR
dc.contributor.authorSaraiva, SApt_BR
dc.contributor.authorCatharino, RRpt_BR
dc.contributor.authorCoelho, Mpt_BR
dc.contributor.authorSchwab, Npt_BR
dc.contributor.authorGarcia, CMpt_BR
dc.contributor.authorSchuchardt, Upt_BR
dc.contributor.authorde Souza, Vpt_BR
dc.contributor.authorEberlin, MNpt_BR
unicamp.author.emailpatricia.abdelnur@embrapa.brpt_BR
unicamp.authorAbdelnur, Patricia V. EMBRAPA Agroenergy, Brazilian Enterprise Agr Res, Natl Ctr Agroenergy Res, BR-34484246 Brasilia, DF, Brazilpt_BR
unicamp.authorAbdelnur, Patricia V. Saraiva, Sergio A. Catharino, Rodrigo R. Coelho, Mirela Schwab, Nicolas Eberlin, Marcos N. Univ Estadual Campinas, Inst Chem, ThoMSon Mass Spectrometry Lab, BR-13083970 Campinas, SP, Brazilpt_BR
unicamp.authorCatharino, Rodrigo R. Univ Estadual Campinas, Sch Med Sci, Innovare Biomarkers Lab, BR-13083970 Campinas, SP, Brazilpt_BR
unicamp.authorGarcia, Camila M. Schuchardt, Ulf Univ Estadual Campinas, Inst Chem, Phoenix Lab, BR-13083970 Campinas, SP, Brazilpt_BR
unicamp.authorde Souza, Vanderlea Directorate Ind & Sci Metrol, Div Chem Metrol, Natl Inst Metrol Standardizat & Ind Qual, BR-25250020 Duque De Caxias, RJ, Brazilpt_BR
dc.subjectmass spectrometrypt_BR
dc.subjectelectrospray ionizationpt_BR
dc.subjectVenturi easy ambient sonic-spray ionizationpt_BR
dc.subjectsoybean biodieselpt_BR
dc.subject.wosSonic-spray Ionizationpt_BR
dc.subject.wosNear-infrared Spectroscopypt_BR
dc.subject.wosMagnetic-resonance-spectroscopypt_BR
dc.subject.wosQuality-controlpt_BR
dc.subject.wosDiesel Blendspt_BR
dc.subject.wosTransesterification Reactionpt_BR
dc.subject.wosMultivariate Calibrationpt_BR
dc.subject.wosOil Transesterificationpt_BR
dc.subject.wosGas-chromatographypt_BR
dc.subject.wosRaman-spectroscopypt_BR
dc.description.abstractQuantitation and identification of blends of soybean biodiesel with petrodiesel were performed via mass spectrometry using two ionization techniques: electrospray ionization (ESI) and Venturi easy ambient sonic-spray ionization in its liquid mode (V-L-EASI). Different soybean biodiesel/petrodiesel blends (from B0 to B100) were diluted and then directly infused and analyzed by both techniques. To investigate adulteration of Bn blends, different soybean oil/biodiesel and soybean oil/petrodiesel blends were analyzed. Analytical curves were obtained in three replicates. The two techniques were shown to provide reasonably accurate quantitation in the B1-B20 range. These techniques were also successfully used to detect contamination or adulteration of Bn blends with vegetable oils. ESI is a widely used and commercially available technique whereas a V-L-EASI source can be easily mounted using common laboratory parts requiring no use of high voltages. Both techniques require no pre-separation or derivatization steps and offer, therefore, simple and fast methods for the quantitation of Bn blends. The comprehensive snapshots of the molecular composition also allow quality control and typification of the biodiesel and eventually of the vegetable oils in illegal admixtures.pt
dc.relation.ispartofJournal Of The Brazilian Chemical Societypt_BR
dc.relation.ispartofabbreviationJ. Braz. Chem. Soc.pt_BR
dc.publisher.citySao Paulopt_BR
dc.publisher.countryBrasilpt_BR
dc.publisherSoc Brasileira Quimicapt_BR
dc.date.issued2013pt_BR
dc.date.monthofcirculationJUNpt_BR
dc.identifier.citationJournal Of The Brazilian Chemical Society. Soc Brasileira Quimica, v. 24, n. 6, n. 946, n. 952, 2013.pt_BR
dc.language.isoenpt_BR
dc.description.volume24pt_BR
dc.description.issuenumber6pt_BR
dc.description.firstpage946pt_BR
dc.description.lastpage952pt_BR
dc.rightsabertopt_BR
dc.sourceWeb of Sciencept_BR
dc.identifier.issn0103-5053pt_BR
dc.identifier.eissn1678-4790pt_BR
dc.identifier.wosidWOS:000321209600008pt_BR
dc.identifier.doi10.5935/0103-5053.20130120pt_BR
dc.description.sponsorshipConselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)pt_BR
dc.description.sponsorshipFundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)pt_BR
dc.description.sponsorshipFundação de Amparo à Pesquisa do Estado do Rio de Janeiro (FAPERJ)pt_BR
dc.description.sponsorshipFINEPpt_BR
dc.description.sponsorship1Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)pt_BR
dc.description.sponsorship1Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)pt_BR
dc.date.available2014-07-30T13:52:28Z
dc.date.available2015-11-26T16:42:00Z-
dc.date.accessioned2014-07-30T13:52:28Z
dc.date.accessioned2015-11-26T16:42:00Z-
dc.description.provenanceMade available in DSpace on 2014-07-30T13:52:28Z (GMT). No. of bitstreams: 0 Previous issue date: 2013en
dc.description.provenanceMade available in DSpace on 2015-11-26T16:42:00Z (GMT). No. of bitstreams: 0 Previous issue date: 2013en
dc.identifier.urihttp://www.repositorio.unicamp.br/jspui/handle/REPOSIP/55769
dc.identifier.urihttp://repositorio.unicamp.br/jspui/handle/REPOSIP/55769-
Appears in Collections:Unicamp - Artigos e Outros Documentos

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