Please use this identifier to cite or link to this item: http://repositorio.unicamp.br/jspui/handle/REPOSIP/55027
Type: Artigo de periódico
Title: Assistant template and co-template agents in modeling mesoporous silicas and post-synthesizing organofunctionalizations
Author: Oliveira, VV
Airoldi, C
Abstract: Mesoporous SBA-16 silicas were synthesized through a direct methodology using the template (F127) combined with co-templates (ethanol and n-butanol), with tetraethylorthosilicate as the silica source. These ordered mesoporous silica were characterized by elemental analyses, infrared spectroscopy, solid-state nuclear magnetic resonance for C-13 (CP/MAS) and Si-29 (HP/DEC) nuclei, nitrogen sorption/desorption processes, small angle X-ray analyses (SAXS) and transmission electron microscopy (TEM). SAXS and TEM results confirmed the space group Im3m and cubic 3D symmetry, typical for highly ordered SBA-16. The sorption/desorption data for SBA-16 and when functionalized gave type IV isotherms, with hysteresis loop H2. Surface areas of 836; 657 and 618 m(2) g(-1) and average pore diameters of 7.99; 8.10 and 9.85 nm, for SBA-16A, SBA-16B and SBA-16C were obtained, respectively. When functionalized the silicas presented a reduction in surface area, pore volume and pore diameter due to the pendant chains that interfere with nitrogen sorption in these measurements. The co-template ethanol favors the ordered mesopores with highest wall thicknesses. (C) 2012 Elsevier Inc. All rights reserved.
Subject: SBA-16
Template
Co-template
Functionalization
Grafting
Country: EUA
Editor: Academic Press Inc Elsevier Science
Rights: fechado
Identifier DOI: 10.1016/j.jssc.2012.05.042
Date Issue: 2012
Appears in Collections:Unicamp - Artigos e Outros Documentos

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